I expected Fye's voice to be a little more feminine though... (In which yes, Fye's seiyuu is also a guy. For those who watched Onegai Twins, he voiced Maiku) and I found Toua's voice a little too deep... but I know I'll get used to it. Same goes with everyone else...
Yeah, Sakura's new seiyuu sounds a little inexperienced but at least she's trying so I'll give her credit for that. I hope by the end of this series, her voice acting would've improved.
As for Syaoran, I found it a little hard to take in. I still miss Kumai Motoko! But I know I'll get used to it... I almost melted when I heard him at the end of the first episode "Onegai desu! Sakura wo tasukete kudasai!"

Kurogane... Can't say much. He only stood out more when he was laughing on that roof... and that makes a very freaky first impression in seiyuu terms. @.@